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Nanofiltration refers to a specialty-membrane processthat rejects dissolved solutes in the approximate size range of 1 nanometer (10Angstroms) — hence the term “nanofiltration.”
With respect to the size and weight of solutes thatnanofiltration membranes reject, NF operates in the realm between reverse osmosis (RO) and ultrafiltration (UF) : Nanofiltration membranes can effectively reject,among other contaminants:
▸ Dissolved organics.
▸ Endotoxins/pyrogens.
▸ Insecticides/pesticides.
▸ Herbicides.
▸ Antibiotics.
▸ Nitrates.
▸ Sugars.
▸ Latex emulsions.
▸ Metal ions.
It also rejects certain soluble salts. Specifically, NF rejects dissolved saltsin the range of 20 – 98 percent. Salts which have monovalent anions (e.g.,sodium chloride or calcium chloride) have rejections of 20 – 80 percent,whereas salts with divalent anions (e.g., magnesium sulfate) have higherrejections of 90 – 98 percent. Transmembrane pressures are typically 50 – 225psi (3.5 – 16 bar).
The ideal nanofiltration membrane has a very high-waterpermeability, but the ideal permeability of solutes might be near zero or somehigher value, depending on the solute and application. For example, an applicationmay require near-zero permeability for pesticides and 50 percent permeabilityfor calcium ions.
Typical applications of nanofiltration membrane systemsinclude:
▸ The removal of color and total organiccarbon (TOC) from surface water.
▸ The removal of hardness or radium from wellwater.
▸ The overall reduction of total dissolvedsolids (TDS).
▸ The separation of organic from inorganicmatter in specialty food* and wastewater applications.
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